Ceramic Matrix Composites Obtained by the Reactive Sintering of Boron Carbide with Intermetallic Compounds from the Ti-Si System

Dawid Kozień; Izabella Czekaj; Patrycja Gancarz; Magdalena Ziąbka; Wojciech Wieczorek; Katarzyna Pasiut; Dariusz Zientara; Zbigniew Pędzich

doi:10.3390/ma15238657

Ceramic Matrix Composites Obtained by the Reactive Sintering of Boron Carbide with Intermetallic Compounds from the Ti-Si System

Materials (Basel). 2022 Dec 5;15(23):8657. doi: 10.3390/ma15238657.

Authors

Dawid Kozień¹, Izabella Czekaj¹, Patrycja Gancarz¹, Magdalena Ziąbka¹, Wojciech Wieczorek¹, Katarzyna Pasiut¹, Dariusz Zientara¹, Zbigniew Pędzich¹

Affiliation

¹ Faculty of Materials Science and Ceramics, AGH University of Science and Technology, 30 Mickiewicz Av., 30-059 Kraków, Poland.

Abstract

In this study, we investigated the effect of adding two different intermetallics, Ti₅Si₃ and TiSi₂, for the preparation of TiB₂-SiC-B₄C composites. As part of the research, stoichiometric composites consisting only of two phases TiB₂ and SiC were obtained. The TiB₂-SiC-B₄C composites were prepared via pressureless sintering. The presence of the phases in the sintered composites was confirmed using X-ray diffraction and scanning electron microscopy. The SEM-EDS examination revealed that the TiB₂ and SiC phases were formed during the composite process synthesis and were distributed homogeneously in the B₄C matrix. The obtained results allowed us to usually exceed 2000 °C and the use of specialized equipment for firing, that is, vacuum or protective atmosphere furnaces as well as control and measurement equipment. Such an approach generates high costs that are decisive for the economics of the technological processes. In the case of our compositions, it is possible to lower the temperature to 1650 °C. The TiB₂-SiC-B₄C composites were classified as UHTCs.

Keywords: Ti5Si3; TiSi2; UHTCs (ultra high-temperature ceramics); boron carbide; composites; intermetallic.

Abstract

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