Simultaneous determination of 210Pb and 90Sr and 210Po isolation in sludge samples using a plastic scintillation resin

Abstract

This study describes a new and fast method for separating ²¹⁰Po from ²¹⁰Pb and ⁹⁰Sr, before simultaneously measuring the individual activities of the latter two radionuclides using a plastic scintillation resin (PSresin) in sludge samples taken from a drinking water treatment plant. This method speeds up the analysis process significantly by simultaneously measuring ²¹⁰Pb and ⁹⁰Sr in a single step. The method is reproducible and has a relative standard deviation of less than 25% for ²¹⁰Pb, ²¹⁰Po and ⁹⁰Sr. The method was satisfactorily validated with an intercomparison sample and applied to sludge samples from a drinking water treatment plant. The minimum detectable activities for 0.9 g of sludge are 5.5 Bq/kg and 8 Bq/kg for ²¹⁰Pb and ⁹⁰Sr respectively when measured for 180 min, and 0.5 Bq/kg for ²¹⁰Po when measured for 5000 min.

Keywords: DWTP; Pb-210; Plastic scintillation resin; Po-210; Sludge; Sr-90.