Sorptive removal of per- and polyfluoroalkyl substances from aqueous solution: Enhanced sorption, challenges and perspectives

Abstract

Per- and polyfluoroalkyl substances (PFASs) have garnered attention globally given their ubiquitous occurrence, toxicity, bioaccumulative potential, and environmental persistence. Sorption is widely used to remove PFASs given its simplicity and cost-effectiveness. This article reviews recently fabricated sorbents, including carbon materials, minerals, polymers, and composite materials. The characteristics and interactions of the sorbents with PFASs are discussed to better understand sorptive processes. Various sorbents have exhibited high removal rates for legacy perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). Novel polymers with special design better remove long- and short-chain PFASs than other sorbents. Although hydrophobic and electrostatic interactions mainly drive the sorption of anionic, cationic, and zwitterionic PFASs, enhancing PFAS sorption on designed sorbents has mainly depended on improving electrostatic interactions. Pearson correlation analysis showed that PFOS sorption capacity of sorbents is positively correlated with their specific surface area. Newly discovered pathways, including the air-water interfacial adsorption, F-F fluorophilic interactions, and (hemi) micelle formation, can enhance PFAS sorption to a certain extent. In addition to PFOA and PFOS, the sorption of emerging PFASs, including aqueous film-forming foam-relevant PFASs, constitutes a new research direction. The functionalization methods for enhancing PFAS sorption and challenges of PFAS sorption are also discussed to provide scope for future research. The discussions herein may contribute to developing efficient sorption technologies to remove PFASs.

Keywords: AFFF-impacted water; Long- and short-chain PFASs; Sorbents; Sorption; Sorption mechanisms.