Accurate estimates of spatiotemporally resolved Polychlorinated dibenzo-p-dioxins (PCDD/Fs, or dioxins) emissions are critical for understanding their environmental fate and associated health risks. In this study, by utilizing an empirical regression model for PCDD/Fs emissions, we developed a global emission inventory for 17 toxic PCDD/Fs congeners from 8 source sectors with a spatial resolution of 1° × 1° from 2002 to 2018. The results show that PCDD/Fs emissions decreased by 25.7 % (12.5 kg TEQ) between 2002 and 2018, mostly occurring in upper- and lower-middle income countries. Globally, open-burning processes, waste incineration, ferrous and nonferrous metal production sectors and heat and power generation were the major source sectors of PCDD/Fs. Spatially, high PCDD/Fs emissions were mainly identified in East and South Asia, Southeast Asia, and part of Sub-Saharan Africa. We find that the declining trend of dioxin emissions over the past decades terminated from the early 2010s due to increasing significance of wildfire induced emissions in the total emission. The PCDD/Fs emission inventory developed in the present study was verified by inputting the inventory as initial conditions into an atmospheric transport model, the Canadian Model for Environmental Transport of Organochlorine Pesticides (CanMETOP), to simulate PCDD/Fs concentrations in air and soil. The predicted concentrations were compared to field sampling data. The good agreement between the modeled and measured concentrations demonstrates the reliability of the inventory.
Keywords: Global; Gridded emission inventory; Modeling; PCDD/Fs; Validation.
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