Si phases with specific shapes, including primary and eutectic Si phases, were etched on the surface of A390 Al alloy by chemical etching. Meanwhile, their effects on the wettability, self-cleaning properties, and mechanical durability of etched A390 aluminum alloy surfaces were investigated. The results showed that the surface etched for 5 min and modified by 1H,1H,2H,2H-perfluorodecyltrimethoxysilane (FAS-17) demonstrated a contact angle of 153.2 ± 1.4° and a sliding angle of 11.2 ± 1.6°. The theoretical contact angle calculated by constructing a wetting model of Si phases approximates the actual contact angle. Further experiments indicated that the etched surface acquired excellent self-cleaning properties. In addition, the exposed Si phases formed a strong support skeleton, which greatly improved the wear resistance of the hydrophobic surface.