Upconversion Luminescence through Cooperative and Energy-Transfer Mechanisms in Yb3+ -Metal-Organic Frameworks

Abstract

Lanthanide-doped metal-organic frameworks (Ln-MOFs) have versatile luminescence properties, however it is challenging to achieve lanthanide-based upconversion luminescence in these materials. Here, 1,3,5-benzenetricarboxylic acid (BTC) and trivalent Yb³⁺ ions were used to generate crystalline Yb-BTC MOF 1D-microrods with upconversion luminescence under near infrared excitation via cooperative luminescence. Subsequently, the Yb-BTC MOFs were doped with a variety of different lanthanides to evaluate the potential for Yb³⁺ -based upconversion and energy transfer. Yb-BTC MOFs doped with Er³⁺ , Ho³⁺ , Tb³⁺ , and Eu³⁺ ions exhibit both the cooperative luminescence from Yb³⁺ and the characteristic emission bands of these ions under 980 nm irradiation. In contrast, only the 497 nm upconversion emission band from Yb³⁺ is observed in the MOFs doped with Tm³⁺ , Pr³⁺ , Sm³⁺ , and Dy³⁺ . The effects of different dopants on the efficiency of cooperative luminescence were established and will provide guidance for the exploitation of Ln-MOFs exhibiting upconversion.

Keywords: Cooperative Luminescence; Energy Transfer; Lanthanides; Metal-Organic Frameworks; Upconversion Luminescence.