Lignin nanoparticles-reduced graphene oxide based hydrogel: A novel strategy for environmental applications

Abstract

In this work, facile fabrication of lignin nanoparticles (L_NP)-based three-dimensional reduced graphene oxide hydrogel (rGO@L_NP) has been demonstrated as a novel strategy for environmental applications. Herein, L_NP were facilely synthesized from walnut shell waste through a direct chemical route. These L_NP were incorporated into the continuous porous network of rGO network to fabricate rGO@L_NP hydrogel. Characterization studies were carried out using various analytical techniques viz. scanning electron microscopy, Fourier transform IR spectroscopy, X-ray diffraction and thermogravimetric analysis. The efficiency of rGO@L_NP hydrogel as adsorptive platform was evaluated by employing methylene blue and Pb²⁺ as model pollutants, whilst the effect of various experimental parameters was ascertained for optimal performance. Furthermore, Agar well diffusion method was used to check the antibacterial activities of the hydrogel using two bacterial pathogenic strains, i.e. Klebsiella pneumoniae (gram negative) and Enterococcus faecalis (gram positive). Results showed that after the inclusion of L_NP into rGO hydrogel, there was a marked improvement in pollutant's uptake ability and compared to bare L_NP and rGO, the composite hydrogel showed enhanced bactericidal effect. Overall, this approach is outstanding because of the synergy of functional properties of nano-lignin and rGO due to multi-interaction sites in the resulting hydrogel. The results presented herein support the application of rGO@L_NP as innovative water filter material for scavenging broad spectrum pollutants and bactericidal properties.

Keywords: Environmental remediation; Lignin nanoparticles; Reduced graphene oxide hydrogel.