Antibiotics have been a primary environmental concern due to their widespread dispersion, harmful bioaccumulation, and resistance to mineralization. Unfortunately, typical processes in wastewater treatment plants are insufficient for complete antibiotic removal, and their derivatives in effluent can pose a threat to human health and aquatic communities. Adsorption and photocatalysis are proven to be the most commonly used and promising tertiary treatment methods. Carbon-based materials, especially those based on graphene, carbon nanotube, biochar, and hierarchical porous carbon, have attracted much attention in antibiotic removal as green adsorbents and photocatalysts because of their availability, unique pore structures, and superior physicochemical properties. This review provides an overview of the characteristics of the four most commonly used carbonaceous materials and their applications in antibiotic removal via adsorption and photodegradation, and the preparation of carbonaceous materials and remediation properties regarding target contaminants are clarified. Meanwhile, the fundamental adsorption and photodegradation mechanisms and influencing factors are summarized. Finally, existing problems and future research needs are put forward. This work is expected to inspire subsequent research in carbon-based adsorbent and photocatalyst design, particularly for antibiotics removal.
Keywords: adsorption; antibiotics; biochar; carbon nanotube; carbon-based materials; graphene; hierarchical porous carbon; photocatalysis.