Lithium-ion batteries (LIBs) are at the forefront of energy storage and highly demanded in consumer electronics due to their high energy density, long battery life, and great flexibility. However, LIBs usually suffer from obvious capacity reduction, security problems, and a sharp decline in cycle life under low temperatures, especially below 0 °C, which can be mainly ascribed to the decrease in Li+ diffusion coefficient in both electrodes and electrolyte, poor transfer kinetics on the interphase, high Li+ desolvation barrier in the electrolyte, and severe Li plating and dendrite. Targeting such issues, approaches to improve the kinetics and stability of cathodes are also dissected, followed by the evaluation of the application prospects and modifications between various anodes and the strategies of electrolyte design including cosolvent, blended Li salts, high-concentration electrolyte, and additive introduction. Such designs elucidate the successful exploration of low-temperature LIBs with high energy density and long lifespan. This review prospects the future paths of research for LIBs under cold environments, aiming to provide insightful guidance for the reasonable design of LIBs under low temperature, accelerating their widespread application and commercialization.
Keywords: electrode materials; electrolyte; kinetics; lithium-ion battery; low temperature.