Conventional hydrophobic membrane-based membrane distillation (MD) has been applied for ammonia recovery from an anaerobic digestion (AD) effluent. However, the typical hydrophobic membranes do not have selectivity for ammonia and water vapor, which results in high energy consumption from the water evaporation. To enhance the selectivity during the ammonia recovery process, the functionalized carbon nanotubes (CNTs)/polyvinylidene fluoride (PVDF) nanofiber membranes were fabricated by electrospinning, and the effects of different CNTs and their contents on the performance of nanofiber membranes were investigated. The results indicate that CNTs can be successfully incorporated into nanofibers by electrospinning. The contact angles of the composite membrane are all higher than those of commercial membrane, and the highest value 138° can be obtained. Most importantly, under the condition of no pH adjustment, the ammonia nitrogen transfer coefficient reaches the maximum value of 3.41 × 10-6 m/s, which is about twice higher than that of commercial membranes. The ammonia separation factor of the carboxylated CNT (C-CNT) composite membrane is higher than that of the hydroxylated CNT(H-CNT) composite membrane. Compared with the application of the novel C-CNT composite membrane, the ammonia separation factor is 47% and 25% higher than that of commercial and neat PVDF membranes. This work gives a novel approach for enhancing ammonia and water selectivity during AD effluent treatment.
Keywords: CNTs composite membrane; ammonia recovery; electrospinning; modification; selectivity.