The paper describes an experimental study and the mathematical simulation of the electromembrane transfer of cations of weak electrolytes (namely, ammonium ions), hindered by hydrolysis reactions taking place in the surface layers of the cation exchange membrane. Using the finite element method, we found a solution to the corresponding diffusion-kinetic electrodialysis problem in potentiostatic mode. Based on the experimental data and the results of theoretical simulation, we analyzed the effect of hydrolysis on the concentration polarization of the electromembrane system and the transport characteristics of ions, and suggested a mechanism of transfer of the components of the ammonium nitrate solution through the cation exchange membrane.
Keywords: ammonium nitrate; cation exchange membrane; electrodialysis; electromass transfer.