Mitigation of ammonia and greenhouse gases emissions from urea coated with oil shale residues in a silvopastoral system

J Environ Manage. 2023 Jan 15;326(Pt B):116779. doi: 10.1016/j.jenvman.2022.116779. Epub 2022 Nov 19.

Abstract

The objective of this work was to investigate the viability of using retorted oil shale as urea coating (U + ROS) in the decrease of N losses by ammonia (NH3-N) volatilization. The experiment was carried out in a silvopastoral system with a randomized block design with split-plots. The main treatments consisted of spatial arrangements of the trees, while the subdivision of the plots constituted the surface application of common urea (U) and retorted oil shale-coated urea (U + ROS) for the pasture. In addition to NH3 measurements, fluxes of N2O and CH4 in the soil were determined, as well as soil moisture and contents of mineral N (0-5 cm). Independently of tree spacing, the use of ROS along with urea (U + ROS) showed a mean decrease of 15.9% in the accumulated NH3 volatilization and 24.1% in the peaks of emission, although it was not significantly different from the U treatment (P < 0.10). In addition, it did not increase significantly the N2O and CH4 emissions, evidencing a potential to decrease N losses by ammonia volatilization, with no impact on greenhouse gases emissions from the soil.

Keywords: Methane; Mineral N; Nitrogen fertilization; Nitrous oxide.

MeSH terms

  • Agriculture
  • Ammonia* / chemistry
  • Fertilizers / analysis
  • Greenhouse Gases*
  • Methane / analysis
  • Minerals
  • Nitrous Oxide / analysis
  • Reactive Oxygen Species
  • Soil / chemistry
  • Urea / chemistry

Substances

  • Ammonia
  • Greenhouse Gases
  • Fertilizers
  • Urea
  • Nitrous Oxide
  • Reactive Oxygen Species
  • Soil
  • Minerals
  • Methane