Excellent photocatalytic and antibacterial activities of bio-activated carbon decorated magnesium oxide nanoparticles

Abstract

Green production of nanomaterials are restrict toxic substances and motivated the noxious free environment. Photocatalysis and antibacterial resistance are more promising and efficient fields for their chemical reductants and clean environment. Herein, we adopted a green and simple method for the biosynthesis of MgO NPs using Manilkara zapota as a bio source. Recently, the green synthesis of magnesium oxide nanoparticles has been a keen interest amongst researchers and scientists due to its simplicity eco-friendliness, non-toxic, inexpensive and potential to perform as an antibacterial agent. Activated carbon/Magnesium oxide (AC/MgO) photocatalyst was blended through a simple solution evaporation method. The surface electron microscopy (SEM) study reviles that AC/MgO had smooth and aggregated particles. The Fourier transform infrared (FT-IR) and x-ray diffraction (XRD) study confirms the structural formation and incorporation of nanoparticles into the AC matrix. Results confirmed the flourishing integration of MgO NPs over the activated carbon matrix. The electron movement and valency of AC/MgO photocatalyst reduced the bandgap and their findings were characterized by ultra visible diffuse reflectance spectroscopy (UV-DRS) and x-ray photoelectron spectroscopy (XPS). The blended AC/MgO photocatalyst was analyzed for photodegradation of Rhodamine- B (Rh-B) dye using a UV-visible spectrophotometer. The degradation study projects that the AC/MgO photocatalyst degrades (Rh-B) dye with 99% efficiency under simulated solar irradiation. This efficient degradation of (Rh-B) dye by AC/MgO photocatalyst is ascribed to the synergetic AC as catalytic support and adsorbent and MgO as photocatalyst. Finally, the photocatalytic material shows a better bactericidal effect in both gram-positive bacteria Escherichia coli-745 and gram-negative bacteria Staphylococcus aureus-9779. The AC/MgO photocatalyst is effectively used in bacteriocidal and photocatalytic removal of dyes and can be used for further development of water reuse and bio-medical fields. In addition, this research shows a viable method for synthesizing a cheap and effective AC/MgO for the photocatalytic destruction of organic pollutants.

Keywords: And S.aureus; Bio-activated carbon; E.coli; Green synthesis; Metal oxides; MgO; Photocatalysis.