Constructing NCuS Interface Chemical Bonds over SnS2 for Efficient Solar-Driven Photoelectrochemical Water Splitting

Abstract

The restricted charge transfer and slow oxygen evolution reaction (OER) dynamics tremendously hamper the realistic implementation of SnS₂ photoanodes for photoelectrochemical (PEC) water splitting. Here, a novel strategy is developed to construct interfacial NCuS bonds between NC skeletons and SnS₂ (CuNC@SnS₂ ) for efficient PEC water splitting. Compared with SnS₂ , the PEC activity of CuNC@SnS₂ photoelectrode is tremendously heightened, obtaining a current density of 3.40 mA cm² at 1.23 V_RHE with a negatively shifted onset potential of 0.04 V_RHE , which is 6.54 times higher than that of SnS₂ . The detailed experimental characterizations and theoretical calculation demonstrate that the interfacial NCuS bonds enhance the OER kinetic, reduce the surface overpotential, facilitate the separation of photon-generated carriers, and provide a fast transmission channel for electrons. This work presents a new approach for modulating charge transfer by interfacial bond design in heterojunction photoelectrodes toward promoting PEC performance and solar energy application.

Keywords: N C skeleton; N Cu S bonds; interface chemical bonds; photoelectrochemical water splitting.