The replacement of powdery catalysts with self-supporting alternatives for catalyzing various electrochemical reactions is extremely important for the large-scale commercial application of renewable energy storage and conversion technologies. Metal-organic framework (MOF)-based nanoarrays possess tunable compositions, well-defined structure, abundant active sites, effective mass and electron transport, etc., which enable them to exhibit superior electrocatalytic performance in multiple electrochemical reactions. This review presents the latest research progress in developing MOF-based nanoarrays for electrocatalysis. We first highlight the structural features and electrocatalytic advantages of MOF-based nanoarrays, followed by a detailed summary of the design and synthesis strategies of MOF-based nanoarrays, and then describe the recent progress of their application in various electrocatalytic reactions. Finally, the challenges and perspectives are discussed, where further exploration into MOF-based nanoarrays will facilitate the development of electrochemical energy conversion technologies.
Keywords: carbon dioxide reduction reaction; electrocatalysis; hydrogen evolution reaction; metal-organic framework; methanol oxidation reaction; nanoarrays; overall water splitting; oxygen evolution/reduction reaction; self-supporting; urea oxidation reaction.