Co-hydrothermal carbonization of agricultural waste and sewage sludge for product quality improvement: Fuel properties of hydrochar and fertilizer quality of aqueous phase

Abstract

Hydrothermal carbonization (HTC) is a promising carbon-neutral technology for converting sewage sludge (SS) and agricultural waste into energy. However, HTC-generated aqueous phase (AP) impedes the development of the former. This study investigated the potential of SS with rice husk (RH) and wheat straw (WS) co-HTC to form hydrochar and AP as substitutes for fuel and chemical fertilizer, respectively. Compared with single SS hydrochar, the yield of co-HTC-based hydrochar and higher heating value significantly increased by 10.9%-21.6% and 4.2%-182.7%, reaching a maximum of 72.6% and 14.7 MJ/kg, respectively. Co-HTC improves the safe handling, storage and transportation, and combustion performance of hydrochar. The total nitrogen concentration in AP-SS was 2575 mg/L, accounting for 67.7% of that found in SS. Co-HTC decreased and increased the amine and phenolic components of AP, respectively. AP-SS-RH and AP-SS-WS significantly increased pakchoi dry weight by 45.5% and 49.4%, respectively, compared with AP-SS. The results of the hydroponic experiments with AP instead of chemical fertilizers revealed that AP-SS did not reduce pakchoi dry weight by replacing <20% chemical fertilizers. However, AP-SS-RH or AP-SS-WS replaced 60% chemical fertilizers. Therefore, the co-HTC of SS and agricultural waste increased the AP substitution of chemical fertilizer from 20% to 60%. These findings suggest that the co-HTC of agricultural waste with SS is a promising technology for converting SS into renewable resource products for fuels and N-rich liquid fertilizer while significantly improving fuel and fertilizer quality.

Keywords: Agricultural waste; Aqueous phase; Co-hydrothermal carbonization; Fertilizer; Hydrochar; Sewage sludge.