Defect-selective-etched porous GaN as a buffer layer for high efficiency InGaN/GaN light-emitting diodes

PLoS One. 2022 Nov 17;17(11):e0277667. doi: 10.1371/journal.pone.0277667. eCollection 2022.

Abstract

Substrate-induced biaxial compressive stress and threading dislocations (TDs) have been recognized to severely impair the performance, stability, and reliability of InGaN/GaN light-emitting diodes (LEDs) for quite some time. In this study, a defect-selective-etched (DSE) porous GaN layer is fabricated employing electro-chemical etching and applied as a buffer layer for the development of InGaN/GaN LEDs with high quantum efficiency. Based on the analysis of photoluminescence and micro-Raman spectra, it has been revealed that the overgrown GaN epilayer on the DSE porous GaN has a relatively low TDs and relaxation of compressive stress in comparison to the conventional GaN epilayer. The remarkable improvement in the internal quantum efficiency of the InGaN/GaN LEDs is directly attributable to the strong radiative recombination in InGaN/GaN multi-quantum-wells caused by stress relaxation and TDs annihilation. Our findings indicate that the use of DSE porous GaN as a buffer layer may be a viable approach for producing crystalline GaN epilayers and high-performance LEDs.

Grants and funding

This research was conducted with the support of the Korea Institute of Industrial Technology project "Development of quantum dot-based sensor material and component technology for eye-safe Lidar system (KITECH EM-22-0002) and was a part of the project titled ‘The development of marine-waste disposal system optimized in an island-fishing village’, funded by the Ministry of Oceans and Fisheries, Korea.