Highly efficient removal of Se(IV) using reduced graphene oxide-supported nanoscale zero-valent iron (nZVI/rGO): selenium removal mechanism

Abstract

Se(IV) removal using nanoscale zero-valent iron (nZVI) has been extensively studied. Still, the synergistic removal of Se(IV) by reduced graphene oxide-supported nanoscale zero-valent iron (nZVI/rGO) has not been reported. In this study, nZVI/rGO was successfully synthesized for Se(IV) removal from wastewater. The effects of different environmental conditions (load ratio, dosage, initial pH) on Se(IV) removal by nZVI/rGO were investigated. When the load ratio is 10%, the dosage is 0.3 g/L, the initial pH is 3, and the removal rate is 99%. The adsorption isotherm and kinetics accorded with the Langmuir isotherm and first-order kinetics models (R² > 0.99). The fitted maximum adsorption capacity reached up to 173.53 mg/g. NZVI/rGo and Se(IV) is a spontaneous endothermic reaction (△G < 0, △H > 0) and is characterized by EDS, XRD, and XPS before and after the reaction, to further clarify the reaction mechanism. The XPS narrow spectrum analysis suggested that Se(IV) was reduced to elemental selenium (Se(0)), while the intermediate Fe(II) was oxidized to form hydroxide precipitation. Therefore, nZVI/rGO was favored for Se-contaminated wastewater remediation.

Keywords: Graphene oxide; Nanoscale zero-valent iron; Reaction mechanism; Se(IV) removal.