Challenges and Opportunities of Transition Metal Oxides as Electrocatalysts

Abstract

As a sustainable energy technology, electrocatalytic energy conversion and storage has become increasingly prominent. The oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), nitrogen reduction reaction (NRR), and carbon dioxide reduction reaction (CO₂ RR) are the key steps in the industrial applications of energy conversion and storage. Compared to the widely used precious metal catalysts, less-noble transition metal oxides (TMOs) and TMO-like materials have attracted broad attention as electrocatalysts in the above reactions. In this concept, we summarize the challenges and opportunities of some typical TMOs in electrocatalysis, and modification strategies of TMOs as electrocatalysts are discussed.

Keywords: activity; electrocatalysis; energy conversion and storage; stability; transition metal oxides.