Functionalized graphene oxide/sodium alginate beads with ion responsiveness for uranium trapping

Carbohydr Polym. 2023 Jan 15:300:120259. doi: 10.1016/j.carbpol.2022.120259. Epub 2022 Oct 26.

Abstract

Uranium as a strategic and non-renewable resource has been paid close attention to its efficient recovery and reuse from uranium-containing wastewater. Here, a composite bead was prepared by functionalized graphene oxide and sodium alginate (L-Lys-GO/SA) with ion-stimuli responsiveness for achieving U(VI) adsorption. The L-Lys-GO/SA-60 composite beads can selectively adsorb U(VI) with the maximum adsorption capacity (qmax) of 704.22 mg/g. Interestingly, the composite beads will swell under the stimulation of ions, which is more conducive to rapid solid-liquid separation and U(VI) recovery at low energy consumption. More importantly, the composite beads also exhibit high reusability of U(VI) adsorption with excellent life span of 80.11 % adsorption rate after 9 cycles, meaning that the composite beads and technology may be used in extraction and production for U(VI) from uranium-containing wastewater.

Keywords: Functionalized graphene oxide; Ion responsiveness; Sodium alginate; Swelling; Uranium-containing wastewater.

MeSH terms

  • Adsorption
  • Alginates
  • Ions
  • Kinetics
  • Uranium*
  • Wastewater

Substances

  • Uranium
  • graphene oxide
  • Alginates
  • Waste Water
  • Ions