Polyurethanes are one of the most important groups of polymers for numerous sectors of industry. Their production involves using dangerous components (diisocyanates), thus, in the search for safer synthetic routes, alternative methods yielding non-isocyanate polyurethanes (NIPU) have been investigated. In this study, the synthesis of polyhydroxyurethane from cyclic carbonates was performed. A three-factor, three-level Box-Behnken experimental design was constructed and the reaction time, temperature and reagents' molar ratio were the independent variables. The built model revealed that the viscosity was influenced by all three independent factors, while the mechanical properties and glass transition temperature of the PHUs were affected by the reagents' ratios. An experimental verification of the model proved its accuracy as the mechanical strength and glass transition temperature deviated from the modeled values, by 15% and 7%, respectively.
Keywords: Box–Behnken design; PHU; model; optimization; polyhydroxyurethane.