The features of the electrochemical behavior of experimental heterogeneous ion-exchange membranes with different mass fractions of sulfonated cation-exchange resin (from 45 to 65 wt%) have been studied by voltammetry during electrodialysis. Electromembrane systems with 0.01 M NaCl solution and with a mixed 0.01 M NaCl + 0.05 M phenylalanine (Phe) solution have been investigated. A significant influence of the ion-exchanger content on the parameters of current-voltage curves (CVCs) was established for the first time. Electrodialysis of the sodium chloride solution revealed a decrease in the length of the limiting current plateau and in the resistances of the second and third sections of the CVCs with an increase in the resin content in the membrane. The fact of the specific shape of the CVCs of all studied cation-exchange membrane samples in mixed solutions of the mineral salt and the amino acid was established. A specific feature of current-voltage curves is the presence of two plateaus of the limiting current and two values of the limiting current, respectively. This phenomenon in electromembrane systems with neutral amino acids has not been found before. The value of the first limiting current is determined by cations of the mineral salt, which are the main current carriers in the system. The presence of the second plateau and the corresponding second limiting current is due to the appearance of additional carriers due to the ability of phenylalanine as an organic ampholyte to participate in protolytic reactions. In the cation-exchange electromembrane system with the phenylalanine containing solution, two mechanisms of H+/OH- ion generation through water splitting and acid dissociation are shown. The possibility of the generation of H+/OH- ions at the enriched solution/cation-exchange membrane interface during electrodialysis of amino acid containing solutions is shown for the first time. The results of this study can be used to improve the process of electromembrane demineralization of neutral amino acid solutions by both targeted selection or the creation of new membranes and the selection of effective current operating modes.
Keywords: ampholyte; cation-exchange membrane; current-voltage characteristic; limiting current; resin content; water splitting.