The surface plasmon in the composite composed of the noble metals and the semiconductors is interesting because of the various charges and the potential applications in many fields. Based on a highly ordered 2D polystyrene spheres array, the ordered composite nanocap arrays composed of TiO2 and Ag were prepared by the co-sputtering technique, and the surface morphology was tuned by changing TiO2 sputtering power. When TiO2 sputtering power was 60 W and Ag sputtering power was 10 W, the composite unit arrays showed the nanocap shapes decorated by many composite clusters around. The composite clusters led to the additional local coupling of the electromagnetic fields and significant Surface-Enhanced Raman Scattering (SERS) observations, which was also confirmed by the finite-different time-domain simulation. The SERS-active substrate composed of the composite nanocaps decorated by clusters realized the accurate detection of the thiram with concentrations down to 10-9 M.
Keywords: SERS; TiO2-Ag composite; nanocaps decorated by clusters.