It is challenging to fabricate 3D architectures of conductive hydrogels and impart uniform conductivity at the same time. Here, we demonstrate a one-step 3D printing technique for controlling the 3D structure of hydrogel materials while simultaneously conferring uniform conductivity. The core technology lies in the in situ polymerization of conductive polymers by the diffusion of monomers and redox initiators to an interface. An alginate ink containing ammonium peroxide as a redox initiator is printed in a silica nanoparticle matrix containing a pyrrole monomer. A 3D structure of conductive polypyrrole is uniformly fabricated on the surface of the alginate immediately after the printing. This simple process provides uniform electrical conductivity throughout the bulk structure.
Keywords: alginate; conductive hydrogels; diffusion; interface; matrix-assisted 3D printing; polymerization; polypyrrole.