6-[(tert-Butyl-dimethyl-sil-yl)-oxy]-3-ethenyl-7-meth-oxy-4-[(tri-methyl-sil-yl)ethyn-yl]naphtho-[2,3- c]furan-1(3 H)-one

IUCrdata. 2020 Feb 21;5(Pt 2):x200224. doi: 10.1107/S2414314620002242. eCollection 2020 Feb.

Abstract

The tricyclic core in the title compound, C26H34O4Si2, shows disorder of the furan ring and deviates slightly from planarity, with the largest displacement from the least-squares plane [0.166 (2) Å] for the major disordered part of the methine C atom. To this C atom the likewise disordered vinyl group is attached, lying nearly perpendicular to the tricyclic core. In the crystal, mutual C-H⋯π inter-actions between the methine group of the furan ring and the central ring of the tricyclic core of an adjacent mol-ecule lead to inversion-related dimers.

Keywords: crystal structure; ethynyl group; notoincisol.