Identifying Organic Matter (OM) Types and Characterizing OM Pores in the Wufeng-Longmaxi Shales

Guoliang Xie; Weiduo Hao

doi:10.1021/acsomega.2c04497

Identifying Organic Matter (OM) Types and Characterizing OM Pores in the Wufeng-Longmaxi Shales

ACS Omega. 2022 Oct 17;7(43):38811-38824. doi: 10.1021/acsomega.2c04497. eCollection 2022 Nov 1.

Authors

Guoliang Xie^{1

2}, Weiduo Hao³

Affiliations

¹ School of Civil Engineering & Architechure, Tongling University, Tongling 244000, People's Republic of China.
² State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu University of Technology, Chengdu 610059, People's Republic of China.
³ Department of Earth & Atmospheric Sciences, University of Alberta, Edmonton, Alberta T6E 2E3, Canada.

Abstract

Organic matter (OM) pores are considered to be an important pore type in the Ordovician Wufeng-Silurian Longmaxi Formation shales in the Sichuan Basin, China, because they have a high capacity to store natural gas. However, to the best of our knowledge, research on the characterization and quantitation of different OM pore characteristics is insufficient. In this study, detailed optical microscope and scanning electron microscope (SEM) observations and the pores/particles and cracks analysis system (PCAS) were applied to identify the OM pores and obtain quantitative information on pores such as pore size, surface porosity, form factor, and probability entropy. Moreover, CO₂ and N₂ adsorption experiments were performed to study the properties of pores for samples with different TOC and mineral compositions. The results show the following. (1) Pyrobitumen and kerogen can be distinguished under an optical microscope and SEM; the former can be further divided into pyrobitumen without a fixed shape and pyrobitumen with a certain shape, and the latter contains algal fragments, bacteria-like aggregates, graptolite, and micrinite. The overwhelming number of SEM-visible OM pores are mainly observed in pyrobitumen without a fixed shape, whereas pores in other OM types are complex. A PCAS analysis showed that meso-macropores are developed in pyrobitumen without a fixed shape, whereas pores in algal fragments and bacterial-like aggregates are mainly mesopores. (2) Quartz-rich brittle shale will provide more visible SEM pores compared to clay-rich ductile shale, and carbonates are unfavorable for pore development because they can block the pore as cements. Moreover, the rigid mineral framework, including that constructed by quartz recrystallization and pyrite cementation, and the pore-fluid pressure are favorable for the development of OM pores. (3) Adsorption experiments showed that pyrobitumen makes a great contribution to pore development, including micropores and meso-/macropores. Finally, we propose that the pore parameters (e.g., pore diameter, pore form factor, and deformation) of pyrobitumen without a fixed shape may characterize the enrichment condition of shale gas.