Transport phenomena in microfluidic chips are induced by electric fields and electrolyte concentrations. Liquid flows are often affected by ionic currents driven by electric fields in narrow channels, which are applied in microelectromechanical systems, microreactors, lab-on-a-chip, and so forth. Even though numerical studies to evaluate those local fields have been reported, measurement methods seem to be under construction. To deeply understand the dynamics of ions at the microscale, measurement techniques are necessary to be developed. In this study, we propose a novel method to directly measure electrical potential differences in liquids, local electric fields, and electrical conductivities, using a glass microelectrode. Scanning an electrolyte solution, for example, KCl solutions, with a 1 μm tip under constant ionic current conditions, a potential difference in liquids is locally measured with a micrometer-scale resolution. The conductivity of KCl solutions ranging from 0.56 to 100 mM is evaluated from electric fields locally measured, and errors are within 5% compared with the reference values. It is found that the present method enables us to directly measure local electric fields under constant current and that the electrical conductivity is quantitatively evaluated. Furthermore, it is suggested that the present method is available for various electrical analyses without calibration procedures before measurements.
© 2022 The Authors. Published by American Chemical Society.