9-[3-(9 H-Carbazol-9-yl)-5-iodo-phen-yl]-9 H-carbazole

IUCrdata. 2021 Apr 27;6(Pt 4):x210428. doi: 10.1107/S2414314621004284. eCollection 2021 Apr.

Abstract

In the title compound, C30H19IN2, two independent mol-ecules (A and B) are present in the asymmetric unit, with different conformations. The dihedral angle between the mean planes of the carbazole systems for mol-ecule A is 49.1 (2)° compared to 84.0 (1)° for mol-ecule B. In the crystal, numerous aromatic π-π stacking inter-actions [shortest centroid-centroid separation = 3.7069 (19) Å] help to establish the three-dimensional supra-molecular network.

Keywords: carbazole derivative; crystal structure; supra­molecular network; π–π stacking.

Grants and funding

Funding for this research was provided by: Natural Science Foundation of Fujian Province, China (grant No. 2018J05077).