Energy-efficient electrochemical treatment of paracetamol using a PbO2 anode based on pulse electrodeposition strategy: Kinetics, energy consumption and mechanism

Abstract

The purpose of this research is to study the pulse electrochemical oxidation of paracetamol (PCT) using a novel PbO₂ anode based on pulse electrodeposition strategy (PbO₂-PE). The pulse electrodeposition strategy used to prepare a PbO₂ anode resulted in rougher surface, higher directional specificity of β(101) and more redox couples of Pb⁴⁺/Pb²⁺. Additionally, the oxygen evolution potential (OEP) and charge transfer resistance were also improved. When compared to direct current electrochemical oxidation process, pulse electrolysis in had a slightly higher PCT removal efficiency and active species (·OH and active chlorine) production, while 72.04% of energy consumption was saved. The effects of operating parameters on PCT degradation efficiency and specific energy consumption were studied. The findings suggested that the pulse electrochemical oxidation of PCT followed a pseudo-first-order kinetic model, with PCT removal reaching 98.63% after 60 min of electrolysis under optimal conditions. Possible mechanisms describing reaction pathways for PCT were also proposed. Finally, combinating with the economic feasibility and safety evaluation, we could conclude that pulse electrolysis with a PbO₂-PE electrode was a promising option for improving the practicability of electrochemical treatment for refractory organic wastewater.

Keywords: Active chlorine species; Energy-saving; Paracetamol; PbO(2)-PE electrode; Pulse electrolysis.