Revealing Phosphorus Nitrides up to the Megabar Regime: Synthesis of α'-P3 N5, δ-P3 N5 and PN2

Dominique Laniel; Florian Trybel; Adrien Néri; Yuqing Yin; Andrey Aslandukov; Timofey Fedotenko; Saiana Khandarkhaeva; Ferenc Tasnádi; Stella Chariton; Carlotta Giacobbe; Eleanor Lawrence-Bright; Michael Hanfland; Vitali Prakapenka; Wolfgang Schnick; Igor A Abrikosov; Leonid Dubrovinsky; Natalia Dubrovinskaia

doi:10.1002/chem.202203123

Revealing Phosphorus Nitrides up to the Megabar Regime: Synthesis of α'-P₃ N_5, δ-P₃ N₅ and PN₂

Chemistry. 2022 Nov 7;28(62):e202203123. doi: 10.1002/chem.202203123. Epub 2022 Nov 2.

Authors

Dominique Laniel^{1

2}, Florian Trybel³, Adrien Néri⁴, Yuqing Yin^{1

5}, Andrey Aslandukov^{1

4}, Timofey Fedotenko⁶, Saiana Khandarkhaeva⁴, Ferenc Tasnádi³, Stella Chariton⁷, Carlotta Giacobbe⁸, Eleanor Lawrence-Bright⁸, Michael Hanfland⁸, Vitali Prakapenka⁷, Wolfgang Schnick⁹, Igor A Abrikosov³, Leonid Dubrovinsky⁴, Natalia Dubrovinskaia^{1

3}

Affiliations

¹ Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, 95440, Bayreuth, Germany.
² Centre for Science at Extreme Conditions and, School of Physics and Astronomy, University of Edinburgh, Edinburgh, EH9 3FD, UK.
³ Department of Physics, Chemistry and Biology (IFM), Linköping University, 581 83, Linköping, Sweden.
⁴ Bayerisches Geoinstitut, University of Bayreuth, 95440, Bayreuth, Germany.
⁵ State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, P. R. China.
⁶ Deutsches Elektronen-Synchrotron, Notkestrasse 85, 22607, Hamburg, Germany.
⁷ Center for Advanced Radiation Sources, University of Chicago, Chicago, IL, 60637, USA.
⁸ European Synchrotron Radiation Facility, B.P. 220, 38043, Grenoble Cedex, France.
⁹ Department of Chemistry, University of Munich (LMU), Butenandtstrasse 5-13, 81377, Munich, Germany.

PMID: 36323532
DOI: 10.1002/chem.202203123

Abstract

Invited for the cover of this issue are Dominique Laniel (University of Edinburgh), Florian Trybel (University of Linköping), and their colleagues. The image depicts a bridge built of the newly discovered δ-P₃ N₅ solid with the structure featuring PN₆ units, a previously missing connection between the carbon group elements nitrides and chalcogens nitrides. Read the full text of the article at 10.1002/chem.202201998.