In optics, the refractive index of a material and its spatial distribution determine the characteristics of light propagation. Therefore, exploring both low- and high-index materials/structures is an important consideration in this regard. Hollow cavities, which are defined as low-index bases, exhibit a variety of unusual or even unexplored optical characteristics and are used in numerous functionalities including diffraction gratings, localised optical antennas and low-loss resonators. In this report, we discuss the fabrication of hollow cavities of various sizes (0.2-5 μm in diameter) that are supported by conformal dielectric/metal shells, as well as their specific applications in the ultraviolet (photodetectors), visible (light-emitting diodes, solar cells and metalenses), near-infrared (thermophotovoltaics) and mid-infrared (radiative coolers) regions. Our findings demonstrate that hollow cavities tailored to specific spectra and applications can serve as versatile optical platforms to address the limitations of current optoelectronic devices. Furthermore, hollow cavity embedded structures are highly elastic and can minimise the thermal stress caused by high temperatures. As such, future applications will likely include high-temperature devices such as thermophotovoltaics and concentrator photovoltaics.
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