Pretreatments for delignification are required for the enzymatic saccharification of lignocellulosic biomasses. However, in the current literature, various pretreatment approaches have been applied for the same kinds of biomass. To find the optimum pretreatments for biomaterials containing various lignin contents, in this study, a quantitative comparison was carried out on the delignification performance of 15 categories of pretreatments. In total, 1729 sets of biomass, cellulose, hemicellulose, and lignin recovery data were collected from 214 relevant studies. Box plots and Cate-Nelson-like graphs were applied for analyses. The results showed that alkali, oxidation, organic solvent, and multistep pretreatments generally were better at removing lignin and recovering cellulose. Moreover, among these four categories, alkali pretreatments had the best performance, increasing the saccharification efficiency by approximately five-fold. Considering both delignification performance and saccharification improvement, alkali pretreatments are currently considered to be the optimum pretreatment methods for enzymatic saccharification.
Keywords: Alkali; Ammonia; Deep eutectic solvent; Diluted acids; Ionic liquids; Organic solvent; Organosolv; Steam explosion.
© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.