In this study, the network strength of starch hydrogels was improved by adjusting the pH value (3-11.5) and adding iron ions (Fe3+), and the mechanical properties and swelling properties of the hydrogels were improved. The complex modulus of the starch hydrogel with a pH value of 11.5 and containing Fe3+ was above 3400 Pa. SEM showed that the hydrogel structure became more compact with the increase of pH value. In addition, the hardness of the hydrogel increased from 50.29 g at pH 3.0 to 215.1 g at pH 11.5, while the addition of 0.5 mol/L Fe3+ at pH 11.5 promoted a further hardness increase to 301.8 g. Moreover, the swelling rate of the hydrogel decreased from 670.2 % at pH 7.0 to 464.4 % at pH 11.5, and the addition of 0.5 mol/L Fe3+ further decreased the swelling rate to 191.8 %. Overall, the results indicate that the mechanical properties of starch hydrogels can be improved by making simple adjustments to the pH and the iron ion concentrations.
Keywords: Mechanical properties; Pea starch hydrogel; Swelling rate.
Copyright © 2022 Elsevier B.V. All rights reserved.