Vertical distributions of atmospheric HONO and the corresponding OH radical production by photolysis at the suburb area of Shanghai, China

Siyu He; Shanshan Wang; Sanbao Zhang; Jian Zhu; Zhibin Sun; Ruibin Xue; Bin Zhou

doi:10.1016/j.scitotenv.2022.159703

Vertical distributions of atmospheric HONO and the corresponding OH radical production by photolysis at the suburb area of Shanghai, China

Sci Total Environ. 2023 Feb 1;858(Pt 1):159703. doi: 10.1016/j.scitotenv.2022.159703. Epub 2022 Oct 25.

Authors

Siyu He¹, Shanshan Wang², Sanbao Zhang¹, Jian Zhu¹, Zhibin Sun¹, Ruibin Xue¹, Bin Zhou³

Affiliations

¹ Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP(3)), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China.
² Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP(3)), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China; Institute of Eco-Chongming (IEC), No. 20 Cuiniao Road, Shanghai 202162, China. Electronic address: shanshanwang@fudan.edu.cn.
³ Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP(3)), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China; Institute of Eco-Chongming (IEC), No. 20 Cuiniao Road, Shanghai 202162, China; Institute of Atmospheric Sciences, Fudan University, Shanghai 200433, China.

PMID: 36306851
DOI: 10.1016/j.scitotenv.2022.159703

Abstract

Nitrous acid (HONO) is considered as one of the main sources of the hydroxyl radical (OH), the most relevant oxidant in the atmosphere. Multi-AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements were conducted to obtain the vertical profiles of aerosol and HONO from November 1, 2020 to January 31, 2021 at a suburb site of Shanghai, China. HONO was mainly distributed near the surface, but high values HONO occasionally occurred around 0.7 km, indicating an unaccounted source of daytime HONO at high altitudes. The positive correlation between HONO and aerosols suggested that the photo-enhanced heterogeneous reactions on the aerosol surface were an important source of daytime HONO at high altitudes. To obtain the vertical distribution of OH production by HONO photolysis (P(OH)_HONO), the vertical profiles of photolysis rate of HONO (J_HONO) were calculated by establishing a method of combining observations with empirical relationship based on heterogeneous atmospheric and radiative transfer models. The J_HONO increased approximately linearly with increasing altitudes and the noontime averages value of J_HONO near the ground were 6.68 × 10^-4 s^-1, which was strongly negatively affected by aerosols in the morning and afternoon. The P(OH)_HONO profile varied in different months (November, December, January) that the changes were mainly affected by HONO and J_HONO. P(OH)_HONO was more positively affected by J_HONO at high altitude and noon but greatly influenced by HONO concentrations in the morning and afternoon.

Keywords: Aerosol; HONO; MAX-DOAS; OH radical production; Photolysis rate.

MeSH terms

Aerosols
Atmosphere* / chemistry
China
Nitrous Acid* / analysis
Photolysis

Substances

Nitrous Acid
Aerosols