Rubber asphalt has always been considered to have the most potential for the disposal of waste tires as sustainable infrastructure. However, the covalently cross-linked tire rubber presents an extreme challenge in reusing waste rubbers in roads. Rubberized asphalt with finely dispersed or colloidal structure has been regarded as a potential binder used as road material because of the improved properties in terms of storage stability, easy processing and high content of incorporation. However, the mixing mechanism between the finely dispersed rubber on micro-nano scale with asphalt is still not clear, which restricts its further development as value-added material. Devulcanized rubber (DR) was introduced to improve the compatibility between asphalt and rubber. The basic chemicals of DR and asphalt were introduced based on their structures. Furthermore, the interactions between DR and asphalt were discussed according to the functional elements at different levels, and the concept of DR as "the fifth component" of asphalt was put forward. Finally, high performance, environmental and economic effects and applications of devulcanized-rubber-modified asphalt (DRMA) were discussed. The review is expected to provide a guide for the wide application of DRMA, which is still restricted by poor compatibility and bad stability during processing, storage and recycling.
Keywords: colloidal structure; devulcanized rubber; interactions; mixing mechanism; rubberized asphalt; sustainability.