An 80-million-year sulphur isotope record of pyrite burial over the Permian-Triassic

Sci Rep. 2022 Oct 17;12(1):17370. doi: 10.1038/s41598-022-21542-4.

Abstract

Despite the extensive use of sulphur isotope ratios (δ34S) for understanding ancient biogeochemical cycles, many studies focus on specific time-points of interest, such as the end-Permian mass extinction (EPME). We have generated an 80 million-year Permian-Triassic δ34Sevap curve from the Staithes S-20 borehole, Yorkshire, England. The Staithes δ34Sevap record replicates the major features of the global curve, while confirming a new excursion at the Olenekian/Anisian boundary at ~ 247 million years ago. We incorporate the resultant δ34Sevap curve into a sulphur isotope box model. Our modelling approach reveals three significant pyrite burial events (i.e. PBEs) in the Triassic. In particular, it predicts a significant biogeochemical response across the EPME, resulting in a substantial increase in pyrite burial, possibly driven by Siberian Traps volcanism. Our model suggests that after ~ 10 million years pyrite burial achieves relative long-term stability until the latest Triassic.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Burial
  • Extinction, Biological*
  • Fossils*
  • Iron
  • Sulfides
  • Sulfur Isotopes

Substances

  • Sulfides
  • Sulfur Isotopes
  • pyrite
  • Iron