Titania Nanorods Embedded with 2-Bromo-3-(methylamino)naphthalene-1,4-dione for Dye-Sensitized Solar Cells

Sharad A Mahadik; Habib M Pathan; Sunita Salunke-Gawali; Ray J Butcher

doi:10.1021/acsomega.2c03208

Titania Nanorods Embedded with 2-Bromo-3-(methylamino)naphthalene-1,4-dione for Dye-Sensitized Solar Cells

ACS Omega. 2022 Sep 27;7(40):35595-35609. doi: 10.1021/acsomega.2c03208. eCollection 2022 Oct 11.

Authors

Sharad A Mahadik^{1

2}, Habib M Pathan², Sunita Salunke-Gawali¹, Ray J Butcher³

Affiliations

¹ Department of Chemistry, Savitribai Phule Pune University, Pune 411007, India.
² Advanced Physics Laboratory, Department of Physics, Savitribai Phule Pune University, Pune 411007, India.
³ Department of Chemistry, Howard University, Washington, District of Columbia 20059, United States.

Abstract

In a recent study, TiO₂ nanorod electrodes were prepared by the hydrothermal approach followed by calcination at various temperatures from 300 to 600 °C. The effects of calcination temperature on the morphological and structural properties were investigated. The novel analogue of aminonaphthoquinone(2R-(n-alkylamino)-1,4-naphthoquinone) photosensitizer, viz. BrA1, 2-bromo-3-(methylamino)naphthalene-1,4-dione was synthesized from 2,3-dibromonaphthalene-1,4-dione. X-ray crystallographic data collection and refinement confirm that BrA1 crystallizes in the triclinic space group P 1̅. After loading BrA1, the photosensitizer on the annealed TiO₂ nanorod (TiO₂NR) electrodes, the optical properties of the photoanodes showed broadbands in each of the UV and visible regions, which are attributed to the π →π* and n → π* charge-transfer transitions, respectively. The dye-sensitized solar cell (DSSC) system was formed by loading the BrA1 photosensitizer on TiO₂NR. The electrochemical impedance spectroscopy (EIS) analyses confirm that calcination temperature improves the charge transportation by lowering the resistance path during the photovoltaic process in TiO₂NR (400 °C) photoanode-based DSSCs due to the sufficient photosensitizer adsorption and fast electron injection. Due to the effective light harvesting by the BrA1 photosensitizer and charge transport through the TiO₂ nanorod, the power conversion efficiencies (PCE) of the TiO₂NR (400 °C/BrA1-based) DSSCs were improved for 2-bromo-3-(methylamino)naphthalene-1,4-dione.