Oil-water separation with high efficiency and low energy consumption is a tremendous challenge in the green treatment of oily wastewater. In this paper, a novel filtration method with combined granular media for collaborative removal emulsified oil and suspended solids (SS) was proposed, followed by the exploration of demulsification feasibility and oil removal mechanism. The effect of the operation and structural parameters of the filter bed on oil separation performance was thoroughly investigated, and its feasibility for raw oily wastewater treatment was also explored. A remarkable demulsification performance was observed with the combined granular media filter, and a balance of separation efficiency and pressure drop in the emulsified oily wastewater filtration was also achieved subsequently. Effective oil droplet capture and coalescence were observed with a high speed camera system, and pore clogging could be avoided in combined media. The optimal parameters of the combined media filter (CMF) were concluded to be a combined media ratio of 1:1, a superficial velocity of 0.20 m min-1, and a bed porosity of 58.1%. The average oil and suspended solids concentrations in raw oily wastewater was decreased to 8.4 mg/L and 23.3 mg/L during the pilot-scale operation, which indicated that the novel filter composed of combined media had better performance in collaboratively removing oil and SS, even in the period of fluctuating influent parameters. It is believed that a novel and efficient oil removal method, especially including of emulsified oil removal was provided, which also shows great potential and value for the green treatment of industrial oily wastewater.
Keywords: Combined granular media; Demulsification; Filtration; Oily wastewater; Opposite wettability.
Copyright © 2022 Elsevier Ltd. All rights reserved.