Study of Synergistic Effects of Cu and Fe on P2-Type Na0.67MnO2 for High Performance Na-Ion Batteries

Rui Luo; Junchao Zheng; Zhiwei Zhou; Jingyi Li; Yunjiao Li; Zhenjiang He

doi:10.1021/acsami.2c12894

Study of Synergistic Effects of Cu and Fe on P2-Type Na_0.67MnO₂ for High Performance Na-Ion Batteries

ACS Appl Mater Interfaces. 2022 Oct 26;14(42):47863-47871. doi: 10.1021/acsami.2c12894. Epub 2022 Oct 14.

Authors

Rui Luo^{1

2

3}, Junchao Zheng^{1

2

3}, Zhiwei Zhou^{1

2

3}, Jingyi Li^{1

2

3}, Yunjiao Li^{1

2

3}, Zhenjiang He^{1

2

3}

Affiliations

¹ School of Metallurgy and Environment, Central South University, Changsha, Hunan410083, China.
² National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Central South University, Changsha410083, China.
³ Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Central South University, Changsha410083, China.

PMID: 36239389
DOI: 10.1021/acsami.2c12894

Abstract

P2-type Na_0.67MnO₂ with a stable structure and an open framework can provide numerous channels for fast Na⁺ de/intercalation, for which it is considered to be advantageous in application of the cathode material for Na-ion batteries. However, the complex phase transition occurring during cycling and the lattice distortion triggered by the Jahn-Teller effect severely restrict its development. Herein, the modified Na_0.67MnO₂ with Cu or Fe single-element doping as well as Cu and Fe double-element doping was synthesized by the sol-gel method, and the effects of doping on the crystal structure and electrochemical performances of Na_0.67MnO₂ were studied. It was demonstrated that the phase of the material did not change after the introduction of Cu and Fe elements, and the cycling stability and rate performance were greatly improved by Cu and Fe double-doping owing to their synergistic effect. The Na_0.67Mn_0.92Fe_0.04Cu_0.04O₂ (NMFCO) cathode delivers discharge specific capacities of 110.5 mA h g^-1 at 5 C and 91.8 mA h g^-1 at 10 C and exhibits the high-capacity retention of 94.35% at 1 C and 90.68% at 5 C after 100 cycles. Overall, this study offers a guiding direction for accelerating the modification of P2-type Na_0.67MnO₂ as a cathode active material for high performance Na-ion batteries.

Keywords: Cu and Fe double-doping; Na-ion batteries; P2-type Na0.67MnO2; structural stability; synergistic effect.