This review article presents different electrochemical and spectroelectrochemical techniques used to investigate conjugated polymers. The development of this research area is presented from an over 40-year perspective-the period of research carried out by Professor Mieczyslaw Lapkowski. Initial research involved polymers derived from simple aromatic compounds, such as polyaniline. Since then, scientific advances in the field of conductive polymers have led to the development of so-called organic electronics. Electrochemical and spectroelectrochemical methods have a great influence in the development of organic semiconductors. Their potential for explaining many phenomena is discussed and the most relevant examples are provided.
Keywords: conjugated polymers; electrochemical polymerization; electrochromism; organic semiconductors; polyaniline; polymerization mechanism; spectroelectrochemistry.