A novel waste-based plasticizer derived from modified used palm oil (mUPO) was successfully developed and has been used as a new plasticizer to non-glutinous thermoplastic starch foam to improve their properties. The molecular weight and hydroxyl number of the mUPO was 3150 g/mol and 192.19 mgOH/g, respectively. The effects of mUPO content ranging from 0 to 9 phr were investigated. The results revealed that the optimal mUPO content as an additive was 6 wt%. The addition of mUPO had a direct effect on the mechanical properties and thermal properties. The impact strength increased from 1.30 to 4.55 J/m, while the glass transition temperature (Tg) decreased from 70.83 to 66.50 °C by increasing mUPO from 0 phr to 6 phr in the thermoplastic starch foam. The mUPO, on the other hand, has also the potential to reduce shrinkage from 33.91 to 21.77% and moisture absorption from 5.93 to 1.73% by increasing the content from 0 phr to 6 phr in starch foam. Furthermore, the mUPO helps the forming of the foam structure as measured by SEM, and the mUPO utilization of waste-based material could be a promising green alternative plasticizer for starch components, especially starch foam applications.
Keywords: green plasticizer; non-glutinous starch; properties improvement; thermoplastic starch foam; used palm oil.