Electrical corona discharge is employed in this work to deposit ions on the surface of an optical fiber, creating a strong electric field that is used for poling. Green laser light propagating in the core frees photocarriers that are displaced by the poling field. The technique presented can induce a higher optical nonlinearity than previously obtained in traditional optical poling with internal metal electrodes. To date, a maximum second order nonlinearity 0.13 pm/V has been achieved for a 15 kV corona discharge bias.