A study on signal enhancement of a Raman probe using an optical pickup unit

Heliyon. 2022 Sep 29;8(10):e10802. doi: 10.1016/j.heliyon.2022.e10802. eCollection 2022 Oct.

Abstract

A simplified fabrication method for an optical pickup unit (OPU)-based Raman probe was introduced. The use of OPU tracking mode was examined to increase the Raman signal and reduce background signals. Unlike most Raman systems, the tracking mode of the OPU moves the objective lens in the x (or y) direction, thus resulting in a significantly reduced background signal and increased Raman signal intensity. These results can be explained by two factors, such as reducing the surface scattering of the incident light from the objective lens and decreasing signal blocking by a dot mirror, which depends on the horizontal position of the objective lens. The reproducibility of the OPU Raman in tracking mode is higher than the OPU Raman in normal mode. The peak position deviation was calculated to be around ±3 cm-1. The Raman spectra of normal organic samples were obtained under the same conditions and recorded as per the applied voltage in the OPU tracking mode to validate the fabricated device. The objective lens shifts resulted in increased Raman peaks and reduced background signals. The maximum peak-position difference for all samples was 10 cm-1 compared to reference peaks obtained using a commercial Raman system.

Keywords: Diode laser; Optical pickup unit; Raman spectrometer; Tracking mode.