Molecular level characterization of the effect of roasting on the extractable components of glandless cottonseed by Fourier transform ion cyclotron resonance mass spectrometry

Food Chem. 2023 Mar 1:403:134404. doi: 10.1016/j.foodchem.2022.134404. Epub 2022 Sep 26.

Abstract

Roasting is a technological process in some food applications of agricultural products. To investigate the composition changes of the extractable functional/bioactive components of cottonseed, in this work, glandless cottonseed kernels were roasted at 110, 120, 140 and 150 °C for 15 min, respectively. The UV/vis data of the 80 % ethanol extracts found that roasting increased the level of phenolic compounds. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry of the extracts identified about 44 % to 55 % of total formulas as potential phenolic compounds. Roasting (up to 140 °C) mainly increased carbohydrate-, lignin-, and tannin-like compounds while lipid-like compounds decreased. The compositional changes at 150 °C were less than those at 140 °C, attributed to devolatilization at the higher temperature. The information of chemical profiling of cottonseed and the roasting impact would be greatly useful in enhanced utilization of cottonseed as nutrient and functional foods or food supplements.

Keywords: Cottonseed; Glandless; Roasting; Ultrahigh resolution mass spectrometry; Van Krevelen diagrams.

MeSH terms

  • Cottonseed Oil* / chemistry
  • Cyclotrons*
  • Fourier Analysis
  • Lignin
  • Mass Spectrometry / methods
  • Spectrometry, Mass, Electrospray Ionization / methods

Substances

  • Cottonseed Oil
  • Lignin