Occurrence, controlling factors and noncarcinogenic risk assessment based on Monte Carlo simulation of fluoride in mid-layer groundwater of Huaibei mining area, North China

Abstract

Fluoride groundwater pollution is a major challenge to ensuring a safe groundwater supply for the global community. This study emphasized mid-layer groundwater (MG) as the main water supply source in the Huaibei mining area, North China. A total of 74 groundwater samples were taken to determine the hydrochemistry, source provenance, driving forces of high-fluoride groundwater, and associated probabilistic health risk using Monte Carlo simulation. The fluoride concentration in 55.56 % of the MG samples exceeded the Chinese drinking water permissible limit of 1 mg/L. In addition, MG is characterized by the hydrochemical faces of HCO₃^- type and Na⁺ type, lower Ca²⁺ and higher TDS concentration. Fluoride enrichment was predominantly controlled by the geogenic sources of fluorite dissolution, silicate weathering and lateral supply from the Carboniferous Taiyuan Formation limestone aquifer (CLA). In addition, the driving forces of high-fluoride groundwater were an alkaline environment, low Ca²⁺ concentration, high Na⁺ and HCO₃^- concentration, cation exchange between Ca²⁺ and Na⁺ on the surface of clay minerals, and competitive adsorption of HCO₃^-. The health risk assessment of F^- for noncarcinogenic risk showed that the HQ values of 28.16 % of groundwater samples exceeded the safety limit of 1 for infants, followed by 2.1 % for children and 0 % for both adult females and males. Infants and children are more prone to the impact of excessive F^-. The findings of this study will provide new insights into the geochemical behavior of F^- and the safety of drinking water.

Keywords: Fluoride; Health risk assessment; Mid-layer groundwater; Monte Carlo simulation; Source apportionment.