The calcium alginate-immobilized Co-g-C3N4 composite microspheres as an efficient mediator to activate peroxymonosulfate for degrading organic pollutants

Abstract

Poor water stability and difficult separation severely limited the application of Co-based catalysts in persulfate activation. Herein, for the first time, the calcium alginate-immobilized Co-g-C₃N₄-2 composite microspheres were prepared by a feasible method. Notably, embedding Co ion into g-C₃N₄ can improve its specific surface area and electrochemical activities. More significantly, as-prepared Co-g-C₃N₄-2 microsphere presented excellent catalytic performance in PMS activation for the degradation of TC. For the activation mechanisms of PMS over Co-g-C₃N₄-2 microspheres, the calcium alginate microspheres could mediate the direct electron transfer between TC and PMS, while both radical and nonradical pathways were involved in the activation of PMS over Co-g-C₃N₄-2. Meanwhile, SO₄^•-, OH^•, O₂^•- and ¹O₂ were major reactive oxygen species formed in the Co-g-C₃N₄-2 microsphere/PMS system. Proposed Co-g-C₃N₄-2 microsphere/PMS system still exhibited great degradation ability towards TC over a wide pH range, and co-existing anions had weak influence on TC degradation over Co-g-C₃N₄-2 microsphere/PMS system. Moreover, the construction of Co-g-C₃N₄-2 microspheres not only avoided the release of metal ion from catalyst, but also provided convenience for the recovery of catalyst. In short, current work shared some novel insights into the application of heterogeneous catalysis in persulfate activation for wastewater treatment.

Keywords: Calcium alginate microsphere; Co-doped g-C(3)N(4); Heterogeneous activation; Persulfate; Tetracycline.