Research progresses on the application of perovskite in adsorption and photocatalytic removal of water pollutants

J Hazard Mater. 2023 Jan 15:442:130024. doi: 10.1016/j.jhazmat.2022.130024. Epub 2022 Sep 19.

Abstract

The problem of global water pollution and scarcity of water resources is becoming increasingly serious. Multifunctional perovskites can well drive adsorption and photocatalytic reactions to remove water pollutants. There are many advantages of perovskites, such as abundant oxygen vacancies, easily tunable structural morphology, stable crystal state, highly active metal sites, and a wide photo response range. However, there are few reviews on the simultaneous application of perovskite to adsorption and photocatalytic removal of water pollutants. Thus, this paper discusses the preparation methods of perovskite, the factors affecting the adsorption of water environmental pollutants by perovskite, and the factors affecting perovskite photocatalytic water pollutants. The particle size, specific surface area, oxygen vacancies, electron-hole trapping agents, potentials of the valence band, and conduction band in perovskites are significant influencing factors for adsorption and photocatalysis. Strategies for improving the performance of perovskites in the fields of adsorption and photocatalysis are discussed. The adsorption behaviors and catalytic mechanisms are also investigated, including adsorption kinetics and thermodynamics, electrostatic interaction, ion exchange, chemical bonding, and photocatalytic mechanism. It summarizes the removal of water pollutants by using perovskites. It provides the design of perovskites as high-efficiency adsorbents and catalysts for developing new technologies.

Keywords: Adsorption; Perovskites; Photocatalysis; Wastewater.

Publication types

  • Review
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Environmental Pollutants*
  • Oxygen
  • Wastewater / chemistry
  • Water
  • Water Pollutants*
  • Water Pollutants, Chemical* / chemistry

Substances

  • perovskite
  • Water Pollutants
  • Water Pollutants, Chemical
  • Environmental Pollutants
  • Water
  • Oxygen
  • Waste Water