Multiple forms of marginal and average emission factors have been developed to estimate the carbon emissions of adding technologies, such as electric vehicles or solar panels, to the electricity grid. Different methods can produce very different results and conclusions, indicating that choosing between methods is not trivial. Researchers would therefore like to know how well these emission factors can approximate emission changes in the actual power grid. This question remains unanswered because of the difficulty in characterizing the accuracy of these methods. Ideally, estimates would be compared to measured emission changes, but it is implausible to measure these changes on an actual grid. Instead, we propose testing these emission factor methods in a controlled environment, using an electricity system dispatch model as a reference for comparison. We find that average emission factors have lower accuracy when estimating emissions from demand shifts and observe the same for demand-based marginal emission factors at an hourly resolution. In contrast, incremental and thermal marginal emission factors can reproduce the emission changes of a power grid model under many testing conditions and scenarios. We also find that easier-to-use annual time averages offer similar results to finer time resolutions for marginal and average factors, except demand-based.
Keywords: dispatch model; electricity system model; emission estimate; macro-energy systems; marginal emission factor.