Fast Capture, Collection, and Targeted Transfer of Underwater Gas Bubbles Using Janus-Faced Carbon Cloth Prepared by a Novel and Simple Strategy

ACS Appl Mater Interfaces. 2022 Oct 5;14(39):45013-45024. doi: 10.1021/acsami.2c12027. Epub 2022 Sep 23.

Abstract

Transportation of bubbles in liquids in a controlled fashion is a challenging task and an important subject in numerous industrial processes, including elimination of corrosive gas bubbles in fluid transportation pipes, water electrolysis, reactions between gases, heat transfer, etc. Using superaerophilic surfaces represents a promising solution for bubble movement in a programmed way. Here, a novel and low-cost method is introduced for the preparation of Janus-faced carbon cloth (Janus-CC) using poly(dimethylsiloxane) (PDMS) coating and then burning one side of the carbon cloth/PDMS on an alcoholic burner. The results show that the superhydrophobic face behaves as a superaerophilic surface, while the superhydrophilic side is aerophobic underwater. Subsequently, the Janus-CC is applied for pumpless transport of underwater gas bubbles even under harsh conditions. The movement of gas bubbles on the surface of the Janus-CC is interpreted based on the formed gaseous film on the aerophilic side of the Janus-CC. Various applications of the prepared Janus-CC for underwater bubble transportation, such as underwater gas distributor, gas collector membrane, gas transport for chemical reactions, unidirectional gas membrane, and elimination of gas bubbles in transport pipe, are presented.

Keywords: Janus-faced carbon cloth; bubble transfer; gas bubble capture; poly(dimethylsiloxane) (PDMS); superaerophilic; superhydrophilic; superhydrophobic.