Modern Synthesis and Sintering Techniques of Calcium Copper Titanium Oxide (CaCu3Ti4O12) Ceramics and Its Current Trend in Prospective Applications: A Mini-Review

Nanomaterials (Basel). 2022 Sep 13;12(18):3181. doi: 10.3390/nano12183181.

Abstract

Calcium Copper Titanium Oxide (CaCu3Ti4O12/CCTO) has grasped massive attention for its colossal dielectric constant in high operating frequencies and wide temperature range. However, the synthesis and processing of CCTO directly influence the material's properties, imparting the overall performance. Researchers have extensively probed into these downsides, but the need for a new and novel approach has been in high demand. Modern synthesis routes and advanced non-conventional sintering techniques have been employed to curb the drawbacks for better properties and performance. This review provides a short overview of the modern synthesis and sintering methods that utilize direct pulse current and electromagnetic waves to improve the material's electrical, optical, and dielectric properties in the best ways possible. In addition, the current application of CCTO as a photocatalyst under visible light and CuO's role in the efficient degradation of pollutants in replacement for other metal oxides has been reviewed. This research also provides a brief overview of using CCTO as a photoelectrode in zinc-air batteries (ZAB) to improve the Oxidation-reduction and evolution (ORR/OER) reactions.

Keywords: Calcium Copper Titanium Oxide; dielectric properties; photocatalyst; sintering techniques; synthesis routes; zinc–air batteries.

Publication types

  • Review

Grants and funding

This research received no external funding.